Metal Passivation using Rodine 85 for Sulfuric Acid Pickling - ChemEqual

Derusting and descaling operations on industrial metal components require the use of strong mineral acids like sulfuric acid to maintain surface quality. It employs the use of acid baths for oxidative removal of alkali scales and mineral oxide deposits. But mineral acids have a tendency to corrode metal surfaces as well rendering them distorted by formation of pits and loss of base metal.

To retard the corrosive nature of acids, the pickling liquor used in acid vats is primarily composed of a pickling acid such as sulfuric acid mixed with an acid corrosion inhibitor. These inhibitors do not reduce the efficiency of the liquor but tend to passivates the base metal surface preventing pitting and corrosion. These passivating chemicals greatly reduce maintenance costs and extend equipment life while optimizing acid utilization and quick operations.
Rodine 85 is a low foaming soluble liquid corrosion inhibitor specifically designed for acid baths that use sulfuric acid as the pickling reagent. It is a synergistic organic blend of 1,3-Diethyl Thiourea, Formaldehyde, substituted Triazine & O-Toluidine, Propargyl Alcohol and detergent that is effective on a wide range of metal surfaces and can be ideally dozed over a wide range of acid concentrations. . Rodine 85 serves as an effective inhibitor for phosphoric and acetic acids, as well as sulfamic, citric, oxalic, and sodium bisulfate solutions in pickling and industrial cleaning operations.

It is recommended that dosage of Rodine 85 to be used for pickling should always be in percent by volume of the concentrated acid, regardless of the degree of acid dilution used. Ideal concentration ranges from 0.05 to 0.30 percent by volume of the diluted acid. In addition, it is also recommended that Rodine 85 inhibitor be used at a concentration not less that 0.5% by volume of the concentrated liquid acid or not less that 0.5% by weight of the concentrated solid acid, regardless of the temperature of the industrial cleaning operation.

Long term use of metal components in industries often makes them susceptible to formation of rust and surface distortion by scaling. In order to maintain surface quality and remove rust, acid treatment is employed. The metal parts are dipped in acid baths to oxidize and remove hard scales and rust layers. But since all acids have a corroding tendency with metals, acid treatment forms a root cause for concern particularly due to abrasive and corrosive loss of precious base metal leading to surface pitting and distortion.
Acid inhibitors are administered in acid pickling baths to prevent loss of base metal after proper pickling. It also helps to extend the life of acid baths. Using of inhibitor in acid solution limits the acid attack on base metal, therefore minimizing base metal loss. A potent acid inhibitor helps to alleviate acid attack on the base metal once the scale has been removed, lending protection to the surface and optimizing acid utilization.

Rodine 85 serves as a soluble, low foaming, liquid corrosion inhibitor formulated for use in conventional sulfuric acid pickling operations. It is an amalgamation of 1,3-Diethyl Thiourea, Formaldehyde, substituted Triazine & O-Toluidine, Propargyl Alcohol and detergent. Rodine 85 is effective on any type of steel, and can be used at any acid concentration. Rodine 85 is an effective inhibitor for phosphoric and acetic acids, as well as sulfamic, citric, oxalic, and sodium bisulfate solutions in pickling and industrial cleaning operations.

Rodine 85 dosage greatly depends on the type of metal, the temperature of operation and the sequence of cleaning operation. The recommended amount of Rodine 85 to be used for pickling is always given in percent by volume of the concentrated acid, regardless of the degree of acid dilution used. RODINE 85 should be used at a concentration ranging from 0.05 to 0.30 percent by volume of the diluted acid regardless of the degree of acid dilution used. In addition, it is recommended that Rodine 85 inhibitor be used at a concentration not less that 0.5% by volume of the concentrated liquid acid or not less that 0.5% by weight of the concentrated solid acid, regardless of the temperature of the industrial cleaning operation.

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